قراءة كتاب The Chemistry of Hat Manufacturing Lectures Delivered Before the Hat Manufacturers' Association

تنويه: تعرض هنا نبذة من اول ١٠ صفحات فقط من الكتاب الالكتروني، لقراءة الكتاب كاملا اضغط على الزر “اشتر الآن"

‏اللغة: English
The Chemistry of Hat Manufacturing
Lectures Delivered Before the Hat Manufacturers' Association

The Chemistry of Hat Manufacturing Lectures Delivered Before the Hat Manufacturers' Association

تقييمك:
0
No votes yet
المؤلف:
دار النشر: Project Gutenberg
الصفحة رقم: 2

say that in certain plants and trees the seeds or fruit are surrounded, in the pods in which they develop, with a downy substance, and that the cotton shrub belongs to this class of plants. A fibre picked out from the mass of the downy substance referred to, and examined under the microscope, is found to be a spirally twisted band; or better,

Fig. 1. Fig. 1.

an irregular, more or less flattened and twisted tube (see Fig. 1). We know it is a tube, because on taking a thin, narrow slice across a fibre and examining the slice under the microscope, we can see the hole or perforation up the centre, forming the axis of the tube (see Fig. 2).

Fig. 2. Fig. 2.

Mr. H. de Mosenthal, in an extremely interesting and valuable paper (see J.S.C.I.,[1] 1904, vol. xxiii. p. 292), has recently shown that the cuticle of the cotton fibre is extremely porous, having, in addition to pores, what appear to be minute stomata, the latter being frequently arranged in oblique rows, as if they led into oblique lateral channels. A cotton fibre varies from 2·5 to 6 centimetres in length, and in breadth from 0·017 to 0·05 millimetre. The characteristics mentioned make it very easy to distinguish cotton from other vegetable or animal fibres. For example, another vegetable fibre is flax, or linen, and this has a very different appearance under the microscope (see Fig. 3). It

Fig. 3. Fig. 3.

has a bamboo-like, or jointed appearance; its tubes are not flattened, nor are they twisted. Flax belongs to a class called the bast fibres, a name given to certain fibres obtained from the inner bark of different plants. Jute also is a bast fibre. The finer qualities of it look like flax, but, as we shall see, it is not chemically identical with cotton, as linen or flax is. Another vegetable fibre, termed "cotton-silk," from its beautiful, lustrous, silky appearance, has excited some attention, because it grows freely in the German colony called the Camaroons, and also on the Gold Coast. This fibre, under the microscope, differs entirely in appearance from both cotton and flax fibres. Its fibres resemble straight and thin, smooth, transparent, almost glassy tubes, with large axial bores; in fact, if wetted in water you can see the water and air bubbles in the tubes under the microscope. A more detailed account of "cotton-silk" appears in a paper read by me before the Society of Chemical Industry in 1886 (see J.S.C.I., 1886, vol. v. p. 642). Now the substance of the cotton, linen or flax, as well as that of the cotton-silk fibres, is termed, chemically, cellulose. Raw cotton consists of cellulose with about 5 per cent. of impurities. This cellulose is a chemical compound of carbon, hydrogen, and oxygen, and, according to the relative proportions of these constituents, it has had the chemical formula C6H10O5 assigned to it. Each letter stands for an atom of each constituent named, and the numerals tell us the number of the constituent atoms in the whole compound atom of cellulose. This cellulose is closely allied in composition to starch, dextrin, and a form of sugar called glucose. It is possible to convert cotton rags into this form of sugar—glucose—by treating first with strong vitriol or sulphuric acid, and then boiling with dilute acid for a long time. Before we leave these vegetable or cellulose fibres, I will give you a means of testing them, so as to enable you to distinguish them broadly from the animal fibres, amongst which are silk, wool, fur, and hair. A good general test to distinguish a vegetable and an animal fibre is the following, which is known as Molisch's test: To a very small quantity, about 0·01 gram, of the well-washed cotton fibre, 1 c.c. of water is added, then two to three drops of a 15 to 20 per cent. solution of [Greek: alpha]-naphthol in alcohol, and finally an excess of concentrated sulphuric acid; on agitating, a deep violet colour is developed. By using thymol in place of the [Greek: alpha]-naphthol, a red or scarlet colour is produced. If the fibre were one of an animal nature, merely a yellow or greenish-yellow coloured solution would result. I told you, however, that jute is not chemically identical with cotton and linen. The substance of its fibre has been termed "bastose" by Cross and Bevan, who have investigated it. It is not identical with ordinary cellulose, for if we take a little of the jute, soak it in dilute acid, then in chloride of lime or hypochlorite of soda, and finally pass it through a bath of sulphite of soda, a beautiful crimson colour develops upon it, not developed in the case of cellulose (cotton, linen, etc.). It is certain that it is a kind of cellulose, but still not identical with true cellulose. All animal fibres, when burnt, emit a peculiar empyreumatic odour resembling that from burnt feathers, an odour which no vegetable fibre under like circumstances emits. Hence a good test is to burn a piece of the fibre in a lamp flame, and notice the odour. All vegetable fibres are easily tendered, or rendered rotten, by the action of even dilute mineral acids; with the additional action of steam, the effect is much more rapid, as also if the fibre is allowed to dry with the acid upon or in it. Animal fibres are not nearly so sensitive under these conditions. But whereas caustic alkalis have not much effect on vegetable fibres, if kept out of contact with the air, the animal fibres are very quickly attacked. Superheated steam alone has but little effect on cotton or vegetable fibres, but it would fuse or melt wool. Based on these differences, methods have been devised and patented for treating mixed woollen and cotton tissues—(1) with hydrochloric acid gas, or moistening with dilute hydrochloric acid and steaming, to remove all the cotton fibre; or (2) with a jet of superheated steam, under a pressure of 5 atmospheres (75 lb. per square inch), when the woollen fibre is simply melted out of the tissue, and sinks to the bottom of the vessel, a vegetable tissue remaining (Heddebault). If we write on paper with dilute sulphuric acid, and dry and then heat the place written upon, the cellulose is destroyed and charred, and we get black writing produced. The principle involved is the same as in the separation of cotton from mixed woollen and cotton goods by means of sulphuric acid or vitriol. The fabric containing cotton, or let us say cellulose particles, is treated with dilute vitriol, pressed or squeezed, and then roughly dried. That cellulose then becomes mere dust, and is simply beaten out of the intact woollen texture. The cellulose is, in a pure state, a white powder, of specific gravity 1·5, i.e. one and a half times as heavy as water, and is quite insoluble in such solvents as water, alcohol, ether; but it does dissolve in a solution of hydrated oxide of copper in ammonia. On adding acids to the cupric-ammonium solution, the cellulose is reprecipitated in the form of a gelatinous mass. Cotton and linen are scarcely dissolved at all by a solution of basic zinc chloride.

Pages