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قراءة كتاب The Chemistry of Hat Manufacturing Lectures Delivered Before the Hat Manufacturers' Association
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The Chemistry of Hat Manufacturing Lectures Delivered Before the Hat Manufacturers' Association
degree of lustre and finish upon hairs thus roughened or partially disintegrated. Figs. 11 and 12 respectively illustrate fur fibres from different parts of the same hare before and after the treatment. In examining one of these fibres from the side of a hare, you see what the cause of this roughness is, and what is also the cause of the difficulty in giving a polish or finish. The free edges are partially disintegrated, etched as it were, besides being caused to stand out. A weaker acid ought to be used, or more mercury and less acid. As we shall afterwards see, another dangerous agent, if not carefully used, is bichrome (bichromate of potassium), which is also liable to roughen and injure the fibre, and thus interfere with the final production of a good finish.
Fig. 11.
Fig. 12.LECTURE II
TEXTILE FIBRES, PRINCIPALLY WOOL, FUR, AND HAIR—Continued
With regard to the preparation of fur by acid mixtures for felting, mentioned in the last lecture, I will tell you what I think I should recommend. In all wool and fur there is a certain amount of grease, and this may vary in different parts of the material. Where there is most, however, the acid, nitric acid, or nitric acid solution of nitrate of mercury, will wet, and so act on the fur, least. But the action ought to be uniform, and I feel sure it cannot be until the grease is removed. I should therefore first wash the felts on the fur side with a weak alkaline solution, one of carbonate of soda, free from any caustic, to remove all grease, then with water to remove alkali; and my belief is that a weaker and less acid solution of nitric acid and nitrate of mercury, and a smaller quantity of it, would then do the work required, and do it more uniformly.
A question frequently asked is: "Why will dead wool not felt?" Answer: If the animal become weak and diseased, the wool suffers degradation; also, with improvement in health follows pari passu, improvement in the wool structure, which means increase both in number and vigour of the scales on the wool fibres, increase of the serrated ends of these, and of their regularity. In weakness and disease the number of scales in a given hair-shaft diminishes, and these become finer and less
Fig. 13.pronounced. The fibres themselves also become attenuated. Hence when disease becomes death, we have considerably degraded fibres. This is seen clearly in the subjoined figures (see Fig. 13), which are of wool fibres from animals that have died of disease. The fibres are attenuated and irregular, the scale markings and edges have almost disappeared in some places, and are generally scanty and meagre in development. It is no wonder that such "dead wool" will be badly adapted for felting. "Dead wool" is nearly as bad as "kempy" wool, in which malformation of fibre has occurred. In such "kemps," as Dr. Bowman has shown, scales have disappeared, and the fibre has become, in part or whole, a dense, non-cellular structure, resisting dye-penetration and felting (see Fig. 14).
Fig. 14.One of the physical properties of wool is its hygroscopicity or power of absorbing moisture. As the very structure of wool and fur fibre would lead us to suppose, these substances are able to absorb a very considerable amount of water without appearing damp. If exposed freely to the air in warm and dry weather, wool retains from 8 to 10 per cent., and if in a damp place for some time, it may absorb as much as from 30 to 50 per cent. of water: Wool, fur, or hair that has been washed, absorbs the most moisture; indeed, the amount of water taken up varies inversely with the fatty or oily matter present. Hence the less fat the more moisture. In the washed wool, those fibres in which the cells are more loosely arranged have the greatest absorbing power for water. No doubt the moisture finds its way in between the cells of the wool fibre from which the oil or fat has been removed. But I need hardly remind you that if wool and fur are capable, according to the circumstances under which they are placed, of absorbing so much moisture as that indicated, it becomes (especially in times of pressure and competition) very important to inquire if it be not worth while to cease paying wool and fur prices for mere water. This question was answered long ago in the negative by our Continental neighbours, and in Germany, France, and Switzerland official conditioning establishments have been founded by the Governments of those countries for the purpose of testing lots of purchased wool and silk, etc., for moisture, in order that this moisture may be deducted from the invoices, and cash paid for real dry wool, etc. I would point out that if you, as hat manufacturers, desire to enter the lists with Germany, you must not let her have any advantage you have not, and it is an advantage to pay for what you know exactly the composition of, rather than for an article that may contain 7 per cent. or, for aught you know, 17 per cent. or 30 per cent. of water. There is, so far as I know, no testing for water in wools and furs in this country, and certainly no "conditioning establishments" (1887), and, I suppose, if a German or French wool merchant or furrier could be imagined as selling wool, etc., in part to a German or French firm, and in part to an English one, the latter would take the material without a murmur, though it might contain 10 per cent., or, peradventure, 30 per cent. of water, and no doubt the foreign, just as the English merchant or dealer, would get the best price he could, and regard the possible 10 per cent. or 30 per cent. of water present with certainly the more equanimity the more of that very cheap element there were present. But look at the other side. The German or French firm samples its lot as delivered, takes the sample to be tested, and that 10 or 30 per cent. of water is deducted, and only the dry wool is paid for. A few little mistakes of this kind, I need hardly say, will altogether form a kind of vade mecum for the foreign competitor.
We will now see what the effect of water is in the felting operation. Especially hot water assists that operation, and the effect is a curious one. When acid is added as well, the felting is still further increased, and shrinking also takes place. As already shown you, the free ends of the scales, themselves softened by the warm dilute acid, are extended and project more, and stand out from the shafts of the hairs. On the whole, were I a hat manufacturer, I should prefer to buy my fur untreated by that nitric acid and mercury process previously referred to, and promote its felting properties myself by the less severe and more rational course of proceeding, such, for example, as treatment with warm dilute acid. We have referred to two enemies standing in the way to the obtainment of a final lustre and finish on felted wool or fur, now let us expose a third. In the black dyeing

