قراءة كتاب The Working of Steel Annealing, Heat Treating and Hardening of Carbon and Alloy Steel

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The Working of Steel
Annealing, Heat Treating and Hardening of Carbon and Alloy Steel

The Working of Steel Annealing, Heat Treating and Hardening of Carbon and Alloy Steel

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دار النشر: Project Gutenberg
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THE ELECTRIC PROCESS

The fourth method of manufacturing steel is by the electric furnace. These furnaces are of various sizes and designs; their size may be sufficient for only 100 lb. of metal—on the other hand electric furnaces for making armor-plate steel will hold 40 tons of steel. Designs vary widely according to the electrical principles used. A popular furnace is the 6-ton Heroult furnace illustrated in Fig. 5.

It is seen to be a squat kettle, made of heavy sheet steel, with a dished bottom and mounted so it can be tilted forward slightly and completely drained. This kettle is lined with special fire brick which will withstand most intense heat and resist the cutting action of hot metal and slag. For a roof, a low dome of fire brick is provided. The shell and lining is pierced in front for a pouring spout, and on either side by doors, through which the raw material is charged.

Two or three carbon "electrodes"—18-in. cylinders of specially prepared coke or graphite—extend through holes in the roof. Electrical connections are made to the upper ends, and a very high current sent through them. This causes tremendous arcs to form between the lower ends of the electrodes and the metal below, and these electric arcs are the only source of heat in this style of furnace.

Electric furnaces can be used to do the same work as is done in crucible furnaces—that is to say, merely melt a charge of carefully selected pure raw materials. On the other hand it can be used to produce very high-grade steel from cheap and impure metal, when it acts more like an open-hearth furnace. It can push the refining even further than the latter furnace does, for two reasons: first the bath is not swept continuously by a flaming mass of gases; second, the temperature can be run up higher, enabling the operator to make up slags which are difficult to melt but very useful to remove small traces of impurities from the metal.

Electric furnaces are widely used, not only in the iron industry, but in brass, copper and aluminum works. It is a useful melter of cold metal for making castings. It can be used to convert iron into steel or vice versa. Its most useful sphere, however, is as a refiner of metal, wherein it takes either cold steel or molten steel from open hearth or bessemer furnaces, and gives it the finishing touches.

Fig. 5 FIG. 5.—"Slagging off" an electric furnace.
Fig. 6 FIG. 6.—Pouring the ingots.

As an illustration of the furnace reactions that take place the following schedule is given, showing the various stages in the making of a heat of electric steel. The steel to be made was a high-carbon chrome steel used for balls for ball bearings:

6-TON HEROULT FURNACE

11:50 A.M. —Material charged:
   Boiler plate 5,980 lb.
   Stampings 5,991 lb.
  11,971 lb.
   Limestone 700 lb.
12:29 P.M. —Completed charging (current switched on).
3:20 P.M. —Charge melted down.
   Preliminary analysis under black slag.
   Analysis:
  
Carbon Silicon Sulphur Phosphorus Manganese
0.06 0.014 0.032 0.009 0.08
   Note the practical elimination of phosphorus.
3:40 P.M. —The oxidizing (black) slag is now poured and skimmed off as clean as possible to prevent rephosphorizing and to permit of adding carburizing materials. For this purpose carbon is added in the form of powdered coke, ground electrodes or other forms of pure carbon.

The deoxidizing slag is now formed by additions of lime, coke and fluorspar (and for some analyses ferrosilicon). The slag changes from black to white as the metallic oxides are reduced by these deoxidizing additions and the reduced metals return to the bath. A good finishing slag is creamy white, porous and viscous. After the slag becomes white, some time is necessary for the absorption of the sulphur in the bath by the slag.

The white slag disintegrates to a powder when exposed to the atmosphere and has a pronounced odor of acetylene when wet.

Further additions of recarburizing material are added as needed to meet the analysis. The further reactions are shown by the following:

3:40 P.M. —Recarburizing material added:
   130 lb. ground electrodes.
   25 lb. ferromanganese.
   Analysis:
  
Carbon Silicon Sulphur Phosphorus Manganese
0.76 0.011 0.030 0.008 0.26

To form white slag there was added:

225 lb. lime.
75 lb. powdered coke.
55 lb. fluorspar.
4:50 P.M.
   Analysis:
  
Carbon Silicon Sulphur Phosphorus Manganese
0.75 0.014 0.012 0.008 0.28

During the white-slag period the following alloying additions were made:

500 lb. pig iron.
80 lb. ferrosilicon.
9 lb. ferromanganese.
146 lb. 6 per cent carbon ferrochrome.

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