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قراءة كتاب The Chemistry, Properties and Tests of Precious Stones

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The Chemistry, Properties and Tests of Precious Stones

The Chemistry, Properties and Tests of Precious Stones

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دار النشر: Project Gutenberg
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id="FNanchor_A_1"/>[A] The value of the enormous crystal was almost beyond computation, but it had a flaw in the centre, and in order to cut out this flaw it was necessary to divide the stone into two pieces. The planes of cleavage were worked out, the diamond was sawn a little, when the operator, acknowledged to be the greatest living expert, inserted a knife in the saw-mark, and with the second blow of a steel rod, the marvellous stone parted precisely as intended, cutting the flaw exactly in two, leaving half of it on the outside of each divided portion. The slightest miscalculation would have meant enormous loss, if not ruin, to the stone, but the greatest feat the world has ever known in the splitting of a priceless diamond was accomplished successfully by this skilful expert in an Amsterdam workroom in February, 1908. Some idea of the risk involved may be gathered from the fact that this stone, the largest ever discovered, in the rough weighed nearly 3,254 carats, its value being almost anything one cared to state—incalculable.

[A] The hammer and knife used in cutting the diamond, the two largest pieces of which are now called "The Stars of Africa," together with a model of the great uncut stone, are in the Tower of London amongst the Regalia.

These cleavage planes help considerably in the bringing of the stone to shape, for in a broad sense, a finished cut stone may be said to be in the form in which its cleavages bring it. Particularly is this seen in the diamond "brilliant," which plainly evidences the four cleavage planes. These cleavage planes and their number are a simple means of identification of precious stones, though those possessing distinct and ready cleavages are extremely liable to "start" or "split" on these planes by extremes of heat and cold, accidental blows, sudden shocks and the like.

In stones possessing certain crystalline structure, the cleavage planes are the readiest, often the only, means of identification, especially when the stones are chemically coloured to imitate a more valuable stone. In such cases the cleavage of one stone is often of paramount importance in testing the cleavage of another, as is seen in the perfection of the cleavage planes of calcite, which is used in the polariscope.

It sometimes happens, however, that false conditions arise, such as in substances which are of no form or shape, and are in all respects and directions without regular structure and show no crystallisation even in the minutest particles; these are called amorphous. Such a condition sometimes enters wholly or partially into the crystalline structure, and the mineral loses its true form, possessing instead the form of crystals, but without a crystalline structure. It is then called a pseudomorph, which is a term applied to any mineral which, instead of having the form it should possess, shows the form of something which has altered its structure completely, and then disappeared. For instance: very often, in a certain cavity, fluorspar has existed originally, but, through some chemical means, has been slowly changed to quartz, so that, as crystals cannot be changed in shape, we find quartz existing—undeniably quartz—yet possessing the crystals of fluorspar; therefore the quartz becomes a pseudomorph, the condition being an example of what is termed pseudomorphism. The actual cause of this curious chemical change or substitution is not known with certainty, but it is interesting to note the conditions in which such changes do occur.

It is found that in some cases, the matrix of a certain shaped crystal may, after the crystal is dissolved or taken away, become filled by some other and foreign substance, perhaps in liquid form; or a crystalline substance may become coated or "invested" by another foreign substance, which thus takes its shape; or actual chemical change takes place by means of an incoming substance which slowly alters the original substance, so that eventually each is false and both become pseudomorphs. This curious change often takes place with precious stones, as well as with other minerals, and to such an extent that it sometimes becomes difficult to say what the stone ought really to be called.

Pseudomorphs are, however, comparatively easy of isolation and detection, being more or less rounded in their crystalline form, instead of having sharp, well-defined angles and edges; their surfaces also are not good. These stones are of little value, except in the specially curious examples, when they become rare more by reason of their curiosity than by their utility as gems.

Some also show cleavage planes of two or more systems, and others show a crystalline structure comprised of several systems. Thus calcspar is in the 2nd, or hexagonal, whilst aragonite is in the 4th, the rhombic, system, yet both are the same substance, viz.:—carbonate of lime. Such a condition is called dimorphism; those minerals which crystallise in three systems are said to be trimorphous. Those in a number of systems are polymorphous, and of these sulphur may be taken as an example, since it possesses thirty or more modifications of its crystalline structure, though some authorities eliminate nearly all these, and, since it is most frequently in either the 4th (rhombic) or the 5th (monoclinic) systems, consider it as an example of dimorphism, rather than polymorphism.

These varieties of cleavage affect the character, beauty and usefulness of the stone to a remarkable extent, and at the same time form a means of ready and certain identification and classification.


CHAPTER V.

PHYSICAL PROPERTIES.

C—Light.

Probably the most important of the many important physical properties possessed by precious stones are those of light and its effects, for to these all known gems owe their beauty, if not actual fascination.

When light strikes a cut or polished stone, one or more of the following effects are observed:—it may be transmitted through the stone, diaphaneity, as it is called; it may produce single or double refraction, or polarisation; if reflected, it may produce lustre or colour; or it may produce phosphorescence; so that light may be (1) transmitted; (2) reflected; or produce (3) phosphorescence.

(1) Transmission.—In transmitted light we have, as stated above, single or double refraction, polarisation, and diaphaneity.

To the quality of refraction is due one of the chief charms of certain precious stones. It is not necessary to explain here what refraction is, for everyone will be familiar with the refractive property of a light-beam when passing through a medium denser than atmospheric air. It will be quite sufficient to say that all the rays are not equal in refractive power in all substances, so that the middle of the spectrum is generally selected as the mean for indexing purposes.

It will be seen that the stones in the 1st, or cubic system, show single refraction, whereas those of all other systems show double refraction; thus, light, in passing through their substance, is deviated, part of it going one way, the other portion going in another direction—that is, at a slightly different angle—so that this property alone will isolate readily all gems belonging to the 1st

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