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قراءة كتاب Soap-Bubbles and the Forces Which Mould Them

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Soap-Bubbles and the Forces Which Mould Them

Soap-Bubbles and the Forces Which Mould Them

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دار النشر: Project Gutenberg
الصفحة رقم: 5

alcohol drops are not by any means so large as the drops of water which are falling by their side. Two possible reasons might be given to explain this. Either alcohol is a heavier liquid than water, which would account for the smaller drop if the skin in each liquid had the same strength, or else if alcohol is not heavier than water its skin must be weaker than the skin of water. As a matter of fact alcohol is a lighter liquid than water, and so still more must the skin of alcohol be weaker than that of water.

Fig. 12.Fig. 12.

We can easily put this to the test of experiment. In the game that is called the tug-of-war you know well enough which side is the strongest; it is the side which pulls the other over the line. Let us then make alcohol and water play the same game. In order that you may see the water, it is coloured blue. It is lying as a shallow layer on the bottom of this white dish. At the present time the skin of the water is pulling equally in all directions, and so nothing happens; but if I pour a few drops of alcohol into the middle, then at the line which separates the alcohol from the water we have alcohol on one side pulling in, while we have water on the other side pulling out, and you see the result. The water is victorious; it rushes away in all directions, carrying a quantity of the alcohol away with it, and leaves the bottom of the dish dry (Fig. 13).

Fig. 13.Fig. 13.

This difference in the strength of the skin of alcohol and of water, or of water containing much or little alcohol, gives rise to a curious motion which you may see on the side of a wine-glass in which there is some fairly strong wine, such as port. The liquid is observed to climb up the sides of the glass, then to gather into drops, and to run down again, and this goes on for a long time. This is explained as follows:—The thin layer of wine on the side of the glass being exposed to the air, loses its alcohol by evaporation more quickly than the wine in the glass. It therefore becomes weaker in alcohol or stronger in water than that below, and for this reason it has a stronger skin. It therefore pulls up more wine from below, and this goes on until there is so much that drops form, and it runs back again into the glass, as you now see upon the screen (Fig. 14). There can be no doubt that this movement is referred to in Proverbs xxiii. 31: "Look not thou upon the wine when it is red, when it giveth his colour in the cup, when it moveth itself aright."

If you remember that this movement only occurs with strong wine, and that it must have been known to every one at the time that these words were written, and used as a test of the strength of wine, because in those days every one drank wine, then you will agree that this explanation of the meaning of that verse is the right one. I would ask you also to consider whether it is not probable that other passages which do not now seem to convey to us any meaning whatever, may not in the same way have referred to the common knowledge and customs of the day, of which at the present time we happen to be ignorant.

Fig. 14.Fig. 14.

Ether, in the same way, has a skin which is weaker than the skin of water. The very smallest quantity of ether on the surface of water will produce a perceptible effect. For instance, the wire frame which I left some time ago is still resting against the water-skin. The buoyancy of the glass bulb is trying to push it through, but the upward force is just not sufficient. I will however pour a few drops of ether into a glass, and simply pour the vapour upon the surface of the water (not a drop of liquid is passing over), and almost immediately sufficient ether has condensed upon the water to reduce the strength of the skin to such an extent that the frame jumps up out of the water.

There is a well-known case in which the difference between the strength of the skins of two liquids may be either a source of vexation or, if we know how to make use of it, an advantage. If you spill grease on your coat you can take it out very well with benzine. Now if you apply benzine to the grease, and then apply fresh benzine to that already there, you have this result—there is then greasy benzine on the coat to which you apply fresh benzine. It so happens that greasy benzine has a stronger skin than pure benzine. The greasy benzine therefore plays at tug-of-war with pure benzine, and being stronger wins and runs away in all directions, and the more you apply benzine the more the greasy benzine runs away carrying the grease with it. But if you follow the directions on the bottle, and first make a ring of clean benzine round the grease-spot, and then apply benzine to the grease, you then have the greasy benzine running away from the pure benzine ring and heaping itself together in the middle, and escaping into the fresh rag that you apply, so that the grease is all of it removed.

There is a difference again between hot and cold grease, as you may see, when you get home, if you watch a common candle burning. Close to the flame the grease is hotter than it is near the outside. It has therefore a weaker skin, and so a perpetual circulation is kept up, and the grease runs out on the surface and back again below, carrying little specks of dust which make this movement visible, and making the candle burn regularly.

You probably know how to take out grease-stains with a hot poker and blotting-paper. Here again the same kind of action is going on.

A piece of lighted camphor floating in water is another example of movement set up by differences in the strength of the skin of water owing to the action of the camphor.

I will give only one more example.

If you are painting in water-colours on greasy paper or certain shiny surfaces the paint will not lie smoothly on the paper, but runs together in the well-known way; a very little ox-gall, however, makes it lie perfectly, because ox-gall so reduces the strength of the skin of water that it will wet surfaces that pure water will not wet. This reduction of the surface tension you can see if I use the same wire frame a third time. The ether has now evaporated, and I can again make it rest against the surface of the water, but very soon after I touch the water with a brush containing ox-gall the frame jumps up as suddenly as before.

It is quite unnecessary that I should any further insist upon the fact that the outside of a liquid acts as if it were a perfectly elastic skin stretched with a certain definite force.

Suppose now that you take a small quantity of water, say as much as would go into a nut-shell, and suddenly let it go, what will happen? Of course it will fall down and be dashed against the ground. Or again, suppose you take the same quantity of water and lay it carefully upon a cake of paraffin wax dusted over with lycopodium which it does not wet, what will happen? Here again the weight of the drop—that which makes it fall if not held—will squeeze it against the paraffin and make it spread out into a flat

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