قراءة كتاب History of Phosphorus

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History of Phosphorus

History of Phosphorus

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hydrogen theory of acids was fundamental for further advance. In another dimension, it is particularly interesting to see that large-scale applications followed almost immediately and directly from the new theoretical insight. The first and foremost of these applications was in agriculture.


Phosphates as Plant Nutrients

One hundred years after the discovery of “cold light,” the presence of phosphorus in plants and animals was ascertained, and its form was established as a compound of phosphoric acid. This knowledge had little practical effect until the “nature” of the acid, in its various forms, was explained through the work of Thomas Graham. From it, there started a considerable technical development.

At about that time (1833), the Duke of Richmond proved that the fertilizing value of bones resided not in the gelatin, nor in the calcium, but in the phosphoric acid. Thus, he confirmed what Théodore de Saussure had said in 1804, that “we have no reason to believe” that plants can exist without phosphorus. Unknowingly at first, the farmer had supplied this element by means of the organic fertilizers he used: manure, excrements, bones, and horns. Now, with the value of phosphorus known, a search began for mineral phosphates to be applied as fertilizers. Jean Baptiste Boussingault (1802-1887), an agricultural chemist in Lyons, traveled to Peru to see the guano deposits. Garcilaso de la Vega (ca. 1540 to ca. 1616) noted in his history of Peru (1604) that guano was used by the Incas as a fertilizer. Two hundred years later, Alexander von Humboldt revived this knowledge, and Humphry Davy wrote about the benefits of guano to the soil. Yet, the application of this fertilizer developed only slowly, until Justus Liebig sang its praise. Imports into England rose and far exceeded those into France where, between 1857 and 1867, about 50,000 tons were annually received.

The other great advance in the use of phosphatic plant nutrients started with Liebig’s recommendation (1840) to treat bones with sulfuric acid for solubilization. This idea was not entirely new; since 1832, a production of a “superphosphate” from bones and sulfuric acid had been in progress at Prague. At Rothamsted in 1842, John Bennet Lawes obtained a patent on the manufacture of superphosphate. Other manufactures in England followed and were successful, although James Muspratt (1793-1886) at Newton lost much time and “some thousands of pounds” on Liebig’s idea of a “mineral manure.”

Figure 8.

Figure 8.—Florida land-pebble phosphate mining. (From Carroll D. Wright, The Phosphate Industry of the United States ..., plate facing page 58.)

It was difficult enough to establish the efficacy of bones and artificially produced phosphates in promoting the growth of plants under special conditions of soils and climate; therefore, the question as to the action of phosphates in the growing plant was not even seriously formulated at that time. The beneficial effects were obvious enough to increase the use of phosphates as plant nutrients and to call for new sources of supply. Active developments of phosphate mining and treating started in South Carolina in 1867, and in Florida in 1888.[25]

In a reciprocal action, more phosphate application to soils stimulated increasing research on the conditions and reactions obtaining in the complex and varying compositions called soil. The findings of bacteriologists made it clear that physics and chemistry had to be amplified by biology for a real understanding of fertilizer effects. After 1900, for example, Julius Stoklasa (1857-1936) pointed out that bacterial action in soil solubilizes water-insoluble phosphates and makes them available to the plants.[26]

Figure 9.

Figure 9.—Florida river-pebble phosphate mining. (From Carroll D. Wright, The Phosphate Industry of the United States ..., plate facing page 64.)

The insight into the importance of phosphorus in organisms, especially since Liebig’s time, is reflected in the work of Friedrich Nietzsche (1844-1900). This “re-valuator of all values” who modestly said of himself: “I am dynamite!” once explained the human temperaments as caused by the inorganic salts they contain: “The differences in temperament are perhaps caused more by the different distribution and quantities of the inorganic salts than by everything else. Bilious people have too little sodium sulfate, the melancholics are lacking in potassium sulfate and phosphate; too little calcium phosphate in the phlegmatics. Courageous natures have an excess of iron phosphate.” (See volume 12 of Nietzsche’s Works, edit. Naumann-Kröner, Leipzig, 1886.) In this strange association of inorganic salts with human temperaments, the role of iron phosphate as a producer of courage is particularly interesting. What would a modern philosopher conclude if he followed the development of insight into the composition and function of complex phosphate compounds in organisms?


From Inorganic to Organic Phosphates

By the middle of the 19th century, the source of phosphorus in natural phosphates and the chemistry of its oxidation products had been established. The main difficulty that had to be overcome was that these oxidation products existed in so many forms, not only several stages of oxidation, but, in addition, aggregations and condensations of the phosphoric acids. Once the fundamental chemistry of these acids was elucidated, the attention of chemists and physiologists turned to the task of finding the actual state in which phosphorus compounds were present in the organisms. It had been a great advance when it had been shown that plants need phosphates in their soil. This led to the next question concerning the materials in the body of the plant for which phosphates were being used and into which they were incorporated. Similarly, the knowledge that animals attain their phosphates from the digested plant food called, in the next step of scientific inquiry, for information on the nature of phosphates produced from this source.

The method used in this inquiry was to subject anatomically separated parts of the organisms to chemical separations. The means for such separations had to be more gentle than the strong heat and destructive chemicals that had been considered adequate up to then. The interpretation of the new results naturally relied on the general advance of chemistry, the development of new methods for isolating substances of little stability, of new concepts concerning the arrangements of atoms in the molecules, and of new apparatus to measure their rates of change.

T. PARKER. ELECTRICAL FURNACE. Patented Sept. 13, 1892. Fig. 1. Fig. 2. Inventor Thomas Parker By his attorneys Howson and Howson Witnesses: George Baumann John Revell

Figure 10.—

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