exploited semiquantitatively by Henry Cavendish in his well-known anticipation of Ohm’s researches. Likewise, Volta in 1800[1] described at length how the application of his pile to suitably placed electrodes on the eyelids, on the tongue, or in the ear, caused stimulation of the senses of sight, taste and hearing; on the other hand, he reported that electrodes in the nose merely produced a “more or less painful” pricking feeling, with no impression of smell. The discharges from the Leyden jars of some of the bigger frictional machines, such as van Marum’s at Leyden, were found by 1785 to magnetize pieces of iron and to melt long pieces of metal wire.[2]

The useful instruments that emerged from all of this experience were various deflecting “electrometers” and “electroscopes” (the words were not carefully distinguished in use), including the important goldleaf electroscope ascribed to Abraham Bennet in 1787.[3]

In 1786, Galvani first observed the twitching of the legs of a dissected frog produced by discharges of a nearby electrostatic machine, thereby revealing still another “effect” of electricity. He then discovered that certain arrangements of metals in contact with the frog nerves produced the same twitching, implying something electrical in the frog-metal situation as a whole. Although Galvani and his nephew Aldini drew from these experiments erroneous conclusions involving “animal electricity,” which were disputed by Volta in his metal-contact theory, it is significant from the instrumentation point of view that the frog’s legs were unquestionably by far the most sensitive detector of metal-contact electrical effects available at the time. Without their intervention the development of this entire subject-area, including the creation of chemical cells, might have been delayed many years. Volta himself realized that the crucial test between his theory and that of Galvani required confirming the existence of metal-contact electricity by some electrical but nonphysiological detector. He performed this test successfully with an electroscope, using the “condensing” technique he had invented more than a decade earlier.

Instrumenting Voltaic or Galvanic Electricity, 1800-1820

In his famous letter of March 20, 1800, written in French from Como, Italy, to the president of the Royal Society in London, Volta made the first public announcement of both his “pile” (the first English translator used the word “column”), and his “crown of cups” (the same translator used “chain of cups” for Volta’s “couronne de tasses”). The former consisted of a vertical pile of circular disks, in which the sequence copper-zinc-pasteboard, was repeated 10 or 20 or even as many as 60 times, the pasteboard being moistened with salt water. The “crown of cups” could be most conveniently made with drinking glasses, said Volta, with separated inch-square plates of copper and zinc in salt water in each glass, the copper sheet in one glass being joined by some intermediate conductor and soldered joints to the zinc in the next glass.

Volta considered the “crown of cups” and the “pile” to be essentially identical, and as evidences of the electrical nature of the latter, said:

The “effects” provided by Volta’s pile and crown-of-cups are therefore electroscope deflection, sparks, and shocks. Later in the letter, he describes the stimulation of sight, taste, and hearing as noted earlier, but nowhere does he mention chemical phenomena of any kind, or the heating of a wire joining the terminals of either device. Hence, except for the additional physiological responses, he adds nothing to the catalog of observations on which instruments might be based. His familiarity with the moods of the torpedo (electric eel) seems to be intimate.

The reading of Volta’s letter to the Royal Society on June 26, 1800, its publication in the Society’s Philosophical Transactions (in French) immediately thereafter, and its publication in English in the Philosophical Magazine for September 1800,[5] gave scientists throughout Europe an easily constructed and continuously operating electric generator with which innumerable new physical, chemical, and physiological experiments could be made. Editor-engineer William Nicholson read Volta’s letter before its publication and, by the end of April, he and surgeon Anthony Carlisle had built a voltaic pile. Applying a drop of water to improve the “connection” of a wire lying on a metal plate, they happened to notice gas bubbles forming on the wire, and pursued the observation to the point of identifying the electrical decomposition of water into hydrogen and oxygen.

Within two or three years innumerable electrochemical reactions had been described, some of which, one might think, could have served as operating principles for electrical instruments. Although the phenomena of gas formation and metal deposition were in fact widely used as crude indicators of the polarity and relative strength of voltaic piles and chemical cells during the period 1800-1820 (and the gas bubbles were made the basis of a telegraph receiver by S. T. Soemmering), the quantitative laws of electrolysis were not worked out by Faraday until after 1830, and not until 1834 was he satisfied that the electrolytic decomposition of water was sufficiently well understood to be made the basis for a useful measuring instrument. Describing his water-electrolysis device in that year, he wrote: