قراءة كتاب The Romance of War Inventions A Description of Warships, Guns, Tanks, Rifles, Bombs, and Other Instruments and Munitions of Warfare, How They Were Invented & How They Are Employed

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The Romance of War Inventions
A Description of Warships, Guns, Tanks, Rifles, Bombs, and Other Instruments and Munitions of Warfare, How They Were Invented & How They Are Employed

The Romance of War Inventions A Description of Warships, Guns, Tanks, Rifles, Bombs, and Other Instruments and Munitions of Warfare, How They Were Invented & How They Are Employed

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دار النشر: Project Gutenberg
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bottom of the vessel, so that there is a means of communication between all three chambers. This is closed, however, by filling the lower part of the vat with mercury up to a level a little higher than the lower ends of the partitions.

Thus we have three separate chambers with communication between them but that communication is sealed up by the mercury.

The two end chambers are filled with salt water, or brine, while the centre one is filled with a solution of caustic soda. In each end compartment is a stick of graphite, both being electrically joined together and so connected up that they form anodes, while in the centre compartment is the cathode.

When the current flows from the anodes it carries the sodium ions with it, just as it did in our little experiment. But its course, this time, is not straight, since in order to travel from anode to cathode it has to pass through the openings in the partitions, in other words through the mercury.

On arrival at or near the cathode the ions of sodium cause the caustic soda to be formed just as in our experiment, but in this case, you will notice, the formation takes place in a chamber from which the salt brine is completely excluded by the mercury.

Brine is continually fed into the outer chambers and the solution of caustic soda is drawn from the centre one, while the chlorine is collected over the anodes.

And now we can go a step further on our progress from common salt to explosive.

In the soap works there are enormous coppers in which are boiled various kinds of fat. The source of the fat may be either animal or vegetable, many kinds of beans, nuts and seeds furnishing fats practically identical with that which can be got from the fat flesh of a sheep, for instance. To this fat is added some caustic soda solution and the whole is kept boiling for some considerable time. This protracted boiling is to enable the soda thoroughly to attack the fat and combine with it, whereby two entirely new substances are formed.

At first the two new substances are not apparent, for they remain together in one liquid. The addition, however, of some brine causes the change to become obvious for something in the liquid turns solid, so that it can be easily taken away from the rest. That solid is nothing else than soap. It remained dissolved in the water which forms part of the liquid until the salt was put in, but as it will not dissolve in salt water, as you will discover if you attempt to wash in sea water, it separates out as soon as the salt is added.

But still a liquid remains: what can that be? It is mainly salt water and glycerine, that sticky stuff which in peace times we put on our hands if they get sore in winter, or take, in a little water, to soothe a sore throat. That it has other and very different uses was brought home to me when, during the war, I tried to buy some at a chemist's, only to learn that it could not be sold except in cases of extreme need under the orders of a doctor.

The mixed liquid is distilled with the result that the water is driven off and the salt deposited, which

with other minor purifying processes gives the pure glycerine.

The next step takes us to the explosives factory, where the glycerine is mixed with sulphuric and nitric acids. Now glycerine, as you will have observed, comes from the animal or vegetable sources and therefore is one of those substances known as "organic," and, like many other of the organic compounds, it consists of carbon, hydrogen and oxygen. Nature has a marvellous way of combining these same three things together in many various ways to form many widely different substances and if, to such a compound, we can add a little nitrogen, we usually get an explosive. Thus, the glycerine, with some nitrogen from the nitric acid, becomes nitro-glycerine, a most ferocious and excitable explosive, the basis of several of those explosives without which warfare as we know it to-day would be impossible.


CHAPTER II
GUNPOWDER AND ITS MODERN EQUIVALENTS

The origin of gunpowder appears to be lost in antiquity. At all events it has been in use for many centuries and is still made in many countries.

Most boys have tried to make it at some time or other and with varying degrees of success. Such experiments generally lead to a glorious blaze, a delightfully horrid smell and no harm to anyone, the experimenter owing his safety to his invariable lack of complete success, for although other and better explosives have superseded it for many purposes it is capable of doing a lot of harm when it is well made.

It consists of a mixture of charcoal, sulphur and saltpetre ground up very fine and mixed very intimately together. The mixture is wetted and pressed into cakes and dried, after which it is broken up into small pieces. The precise proportions of the various materials seem to vary a great deal in different countries, but generally speaking there is about 75 per cent of saltpetre (or to give it its scientific name, nitrate of potash), 15 per cent of charcoal and 10 per cent of sulphur.

Now gunpowder, like all explosives, is simply

some thing or mixture of things which is capable of burning very quickly. When we light the fire we set going the process which we call combustion, or burning, and, as we know from our own experience, that process causes heat to be generated.

What takes place in the fire-grate is that the carbon of the coal enters into combination with oxygen from the air, the two together forming a new compound called "carbonic acid gas." There is nothing lost or destroyed in this process, the carbon and oxygen simply changing into the new substance, and could we weigh the gas produced we should find that it agreed precisely with the weight of the carbon and oxygen consumed. For the purpose for which we require the fire, namely, to heat the room, the chief feature about this process is not what is formed in the shape of gas, for that simply goes off up the chimney, but the heat which is liberated. We believe that in some mysterious way the heat is locked up in the coal. Latent is the term we use, which means hidden: in other words we believe that the heat is hidden in the coal: we cannot feel it or perceive it in any way, but it comes out when we let the carbon combine with the oxygen.

Why these two things combine at all is one of those mysteries which may never be solved. We have theories on the subject, but all we really know is that under certain conditions if they be in contact with one another they will combine, apparently for the simple reason that it is their nature so to do.

When we apply the match to the fire all we do is to set up the conditions under which the carbon and

oxygen are able to follow their natural instincts, so to speak.

A coal fire, as we all know, burns slowly, for the simple reason that it is only at the surface of the lumps that carbon and oxygen are in contact. If we grind up the coal into a fine powder and then blow it into a cloud, so that every tiny particle is surrounded with air, a spark will cause an explosion. That is how these terrible explosions in coal-pits are caused.

This is sometimes seen on a small scale when one shakes the empty fire-shovel after putting coal on the fire to get rid of the fine dust adhering to it and to save making a mess in the fender. That little cloud of fine dust will often burst into flame like a mild explosion.

We see from this that to make an explosion we require fuel, just as we do to make a fire: but we need that it shall be very intimately mixed with oxygen, so that all of it can burn up in practically a

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