قراءة كتاب The Romance of War Inventions A Description of Warships, Guns, Tanks, Rifles, Bombs, and Other Instruments and Munitions of Warfare, How They Were Invented & How They Are Employed
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The Romance of War Inventions A Description of Warships, Guns, Tanks, Rifles, Bombs, and Other Instruments and Munitions of Warfare, How They Were Invented & How They Are Employed
bubbles will soon detach themselves and float up to the surface. Those which arise from one of the leads will be formed of the gas chlorine and the others of hydrogen.
It will be interesting just to enumerate the names of the different parts of this apparatus. First let me say that the process by which these gases are thus obtained is called electrolysis: the liquid is the electrolyte: the two pieces of pencil lead are the electrodes. That electrode by which the current enters the electrolyte is called the an-ode, while the other is the cath-ode. In other words, the current traverses them in alphabetical order.
Now it is familiar to everyone that all matter is supposed to consist of tiny particles called Molecules. These are far too tiny for anyone to see even with the finest microscope, so we do not know for certain that they exist: we assume that they do, however, because the idea seems to fit in with a large number of facts which we can observe and it enables us to talk intelligibly about them. We may, accordingly, speak as if we knew for a certainty that molecules really exist.
Now when we dissolve salt in water it seems as if each molecule splits up into two things which we then call "ions." Salt is not peculiar in this respect, for many other substances do the same when dis
solved in water. All such substances, since they can be "ionized," are called "ionogens."
Now the peculiarity about ions is that they are always strongly electrified or charged with electricity.
At this stage we must make a little excursion into the realm of electricity. You probably know that if a rod of glass be rubbed with a silk handkerchief it becomes able to attract little scraps of paper. That is because the rubbing causes it to become charged with electricity. In like manner a piece of resin if rubbed will become charged and will also attract little pieces of paper. A piece of electrified resin and an electrified glass rod will, moreover, attract each other, but two pieces of resin or two pieces of glass, if electrified, will repel each other. This leads us to believe that there are two kinds of electrification or two kinds of electrical charge. At first these two kinds were spoken of as vitreous or glass electricity and resinous electricity, but after a while the idea arose that there was really one kind of electricity and that everything possessed a certain amount of it, the electrified glass having a little too much of it and the electrified resin a shade too little of it. From this came the idea of calling the charge on the glass a "positive" charge and that on the resin a "negative" charge. Recent investigations seem to show that we have got those two terms the wrong way round, but to avoid confusion we still use them in the old way.
It will be sufficient for our purpose, therefore, if we assume that every molecule of matter has a certain normal amount of electricity associated with it and
that under those conditions the presence of the electricity is not in any way noticeable. When a molecule becomes ionized, however, one ion always seems to run off with more than its fair share of the electricity, the result being that one is electrified positively, like rubbed glass, while the other is negatively charged, like rubbed resin.
Thus, when the common salt is dissolved in water, two lots of ions are formed, one lot positively charged and the other lot negatively. Each molecule of salt consists of two atoms, one of sodium and one of chlorine: consequently, one ion is a chlorine atom and the other is a sodium atom, the latter being positive and the former negative.
Now the electrodes are also charged by the action of the battery. That connected to the positive pole of the battery becomes positively charged and the other negatively. The anode, therefore, is positive and the cathode negative.
It has been pointed out that two similarly charged bodies, such as two pieces of glass or two pieces of resin, repel each other, while either of these attracts one of the other sort. Hence we arrive at a rule that similarly charged bodies repel each other, while dissimilarly charged bodies attract each other.
Acting upon this rule, therefore, the anode starts drawing to itself all the negative ions, in this case the atoms of chlorine, while the cathode gathers together the positive ions, the atoms of sodium. Thus the action of the battery maintains a sorting out process by which the sodium is gathered together around one of the electrodes and the chlorine round the other.
Those ions, by the way, which travel towards the an-ode are called an-ions, while those which go to the cath-ode are termed cat-ions.
Thus far, I think, you will have followed me: the chlorine is gathered to one place and the sodium to the other. The former creates bubbles and floats up to the surface and escapes. But where, you will ask, does the hydrogen come from, which we found, in the experiment, was bubbling up round the cathode. Moreover, what becomes of the sodium?
Both those questions can be answered together. The sodium ions, having been drawn away from their old partners the chlorine ions, are unhappy, and long for fresh partners. They therefore proceed to join up with molecules of water. But water contains too much hydrogen for that. Every molecule of water has two atoms of hydrogen linked up with one of oxygen, but sodium does not like two atoms of hydrogen: it insists on having one only. Accordingly the oxygen atom from the water, together with one of the hydrogen atoms, join forces with the sodium atom into a molecule of a new substance, a most valuable substance in many manufactures, called Caustic Soda, while the odd atom of hydrogen, deprived of its partners, has nothing left to do but to cling for a while to the cathode and finally float up and away.
The sum-total of the operation therefore is this: when we pass an electric current through salt water, between graphite electrodes, chlorine goes to the anode and escapes, while caustic soda is formed round the cathode and hydrogen escapes. Let us see now how this is applied commercially.
For the production of Chlorine the apparatus need be little more than our experimental apparatus made large. The anode can be covered in such a way as to catch the gas as it bubbles upwards. In times of peace this gas is chiefly used for making bleaching powder. It is led into chambers where it comes into contact with lime, with which it combines into chloride of lime, a powder which is sometimes used as a disinfectant, but the chief use of which is for bleaching those cotton and woollen fabrics for the manufacture of which this country is famous throughout the world.
The Germans, however, have taught the world another use for chlorine. Those gallant Canadians who were the first victims of the attack by "poison gas" who suddenly found themselves fighting for breath, and a few of whom, more fortunate than the rest, have reached their homes shattered in health with permanent damage to their lungs, those brave fellows suffered from poisoning by chlorine.
We cannot obtain the other product, the caustic soda, by the same simple means. In our little experiment we succeeded in manufacturing some of it in the region around the cathode, and had we drawn off some of the liquid from there we would have been able to detect its presence. But it would have been mixed up with much ordinary salt, and for commercial purposes we need the caustic soda separate from the salt. The principle is, however, just the same, as you will see.
Imagine a large oblong vat divided by vertical partitions into three separate chambers. These