class="left"> Washington Paint Tests

PAINT TECHNOLOGY

CHAPTER I

PAINT OILS AND THINNERS

Constants and Characteristics of Oils and Their Effect upon Drying. An attempt has been made to give in this chapter a brief summary of the most important characteristics of those oils finding application in the paint and varnish industry. For methods of oil analysis, the reader is referred to standard works on this subject; the analytical constants herein being given only for comparative purposes.

It is well known that one of the most desirable features of a paint oil is the ability to set up in a short period to a hard surface that will not take dust. This drying property is dependent upon the chemical nature of the oil. If it is an unsaturated compound, like linseed oil, rapid absorption of oxygen will cause the film to dry rapidly and become hard. If the oil be of a fully satisfied nature, like mineral oil, oxygen cannot be taken up to any great extent and drying will not take place. The various animal and vegetable oils differ in their power of oxygen absorption to a lesser or greater extent. This difference is referred to by the chemist in terms of the iodine value. The iodine value of linseed oil is approximately 190, meaning that one gram of the oil will take up 190 centigrams of iodine. Oils with high iodine values have good drying powers, while those with low iodine values are, as a rule, very slow drying in nature.

For a description of the working and drying properties of various oils used in paints, see Chapter XIV. The oxygen absorption of various oils and mixtures is shown in Chapter II.

Linseed Oil. The seed of the flax plant which is extensively grown in North Dakota, Argentine Republic and Russia, contains approximately 36% of oil which may be obtained by grinding, heating, and expression. Ripe native seed generally produces a pale oil of little odor; the oil from Argentine seed often having a greenish tint and an odor resembling sorghum. While filtering, pressing and ageing will remove considerable of the (“foots”) mucilaginous matter, phosphates, silica, etc., from the oil, the better grades which are intended for varnish making are often refined with sulphuric acid. A light colored oil which may be heated without “breaking” results from this treatment, but such oils are apt to contain considerable free fatty acid, unless they are washed with alkali subsequent to the sulphuric acid treatment. On account of its rapid drying properties and general adaptability for all classes of paints and varnishes, linseed oil has never been supplanted by any other oil. Chemically it consists of the glycerides of linoleic, oleic, and isolinoleic acid, its constitution being responsible for its very high iodine value.

Field of Flax in bloom in North Dakota

Boiled linseed oil, a heavier and darker product, is made by heating the raw oil in open kettles to high temperatures, generally with the addition of metallic driers such as litharge, and black manganese. The resinates of lead and manganese are often added to oil heated at a lower temperature, to obtain a boiled oil of lighter color.

New type of Flax Harvester which pulls plant up by the roots, thus preventing infection of soil

Modern Concrete Elevators for storing Flaxseed

View of Linseed Oil Factory showing hydraulic press, tanks, etc.

Photographs courtesy of Spencer Kellogg Sons

Flaxseed Crushers

Filter Presses for removing extraneous matter from linseed oil

Linseed Cake from Oil Press

Glycine Hispida
Mammoth soya bean plants

Photographs courtesy of David Fairchild, Plant Explorer, U. S. Dept. of Agriculture

Glycine Hispida
Soya bean plants under cultivation at Arlington, Va.

By blowing air through linseed oil that has been heated to approximately 200 degrees Fahrenheit, either with or without drier, heavy bodied oils are obtained, which find special application in varnishes and technical paints. As the viscosity of these oils increase, the iodine values decrease, and a slight rise in saponification value and