قراءة كتاب Paint Technology and Tests
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such as litharge.
Photographs courtesy of David Fairchild
The affinity of tung oil for rosin has resulted in the production of a series of moderate-priced varnishes most suitable for use in floor and deck paints or wherever great hardness is required. These varnishes are also finding application in the manufacture of concrete, steel, and flat wall paints; being especially suitable for the above purposes when compounded with kauri gum japan.
During the boiling of raw tung oil the temperature must not exceed much over 400 degrees Fahrenheit. Otherwise a peculiar “hamming” will take place, the whole mass becoming solid and of no further value as a varnish or paint vehicle. Some peculiar internal disturbance or rearrangement of the molecules is evidently effected by heat, and although the reaction is not clearly understood, it has been ascribed to auto-polymerization. Scott has stated that the phenomenon of gelatinization is due to the exposure of the surface of the oil to the air, and that boiling in vacuo obviates such results. The lusterless surface produced when tung oil varnishes are dried in vitiated air would tend to confirm the conclusion that the oil is very subject to atmospheric influences.
Lumbang Oil, which is obtained from a tropical species of Tung, is very similar in appearance and properties to Linseed Oil.
Constants of Tung Oils
Sp. Gr. | Iodine No. | Saponifi- cation No. |
Acid No. | |
No. 1 | .944 | 166 | 188 | 3.6 |
No. 2 | .940 | 164 | 184 | 1.8 |
Photographs courtesy Alpin I. Dunn
Menhaden Oil. Of all the marine-animal oils, such as seal, herring, sardine, whale, and menhaden, the latter is the most valuable. It is produced by steam digestion and pressure of the menhaden or “piogey” fish, which are caught in great quantities off the Atlantic Coast. Prompt cooking and treatment of the fish results in a light-colored oil having very little odor, the residue left in the presses being of great value as a fertilizer. Although several grades of oil termed crude, brown, light, etc., are produced, the most satisfactory for use in paint is that grade termed “light winter pressed.” This oil is of a pale straw color and has a high iodine number which is responsible for its rapid drying value. It contains less of the stearates that precipitate from crude oil, but sufficient to render its film water-shedding and elastic. The presence of too great a quantity of stearates is apt to result in a very soft film, and the use of hard driers, such as the metallic tungates, is therefore advisable with menhaden oil. When mixed with linseed oil paints the odor of menhaden oil is sometimes noticeable, but it disappears entirely after such paints are applied. Its use with linseed oil in technical paints exposed to the salty air of the Coast has given good results, often preventing “checking” and “chalking.”
The following constants were determined on samples of menhaden oil received in the writer’s laboratory:
Sp. Gr. | Iodine Value |
Saponification Number |
Acid Number |
|
Light | .927 | 175.8 | 187.9 | 7.55 |
Medium | .925 | 178.7 | 187.6 | 6.19 |
Dark | .927 | 178.0 | 187.3 | 7.19 |
Whale Oil. While ordinary whale oil is too dark and odorous to ever come into extensive use as a paint oil, it is probable that the refined oil will be utilized in the manufacture of certain technical paints. Whale oil is boiled from chopped whale blubber, the first trying being the lightest in color, while the later tryings, as well as the product made from bones, are of darker color and of very bad odor. Oil of mirbane is often used to mask this odor. The oil contains large quantities of stearin and palmitin, as well as wax-like constituents which are apt to be thrown out of solution in very cold weather, or when the oil is mixed with other oils. The refined oil, when ground with lead and zinc pigments and mixed with equal parts of linseed oil and treated tung oil, dries to an elastic and soft film. Experiments are being made to utilize whale oil in the linoleum