قراءة كتاب Encyclopaedia Britannica, 11th Edition, "Matter" to "Mecklenburg" Volume 17, Slice 8
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Encyclopaedia Britannica, 11th Edition, "Matter" to "Mecklenburg" Volume 17, Slice 8
electrical constitution of matter, there will be a part of the mass of any system dependent upon the potential energy and in fact proportional to it. Thus every change in potential energy, such for example as occurs when two elements combine with evolution or absorption of heat, must be attended by a change in mass. The amount of this change can be calculated by the rule that if a mass equal to the change in mass were to move with the velocity of light its kinetic energy would equal the change in the potential energy. If we apply this result to the case of the combination of hydrogen and oxygen, where the evolution of heat, about 1.6 × 1011 ergs per gramme of water, is greater than in any other known case of chemical combination, we see that the change in mass would only amount to one part in 3000 million, which is far beyond the reach of experiment. The evolution of energy by radio-active substances is enormously larger than in ordinary chemical transformations; thus one gramme of radium emits per day about as much energy as is evolved in the formation of one gramme of water, and goes on doing this for thousands of years. We see, however, that even in this case it would require hundreds of years before the changes in mass became appreciable.
The evolution of energy from the gaseous emanation given off by radium is more rapid than that from radium itself, since according to the experiments of Rutherford (Rutherford, Radio-activity, p. 432) a gramme of the emanation would evolve about 2.1 × 1016 ergs in four days; this by the rule given above would diminish the mass by about one part in 20,000; but since only very small quantities of the emanation could be used the detection of the change of mass does not seem feasible even in this case.
On the view we have been discussing the existence of potential energy due to an electric field is always associated with mass; wherever there is potential energy there is mass. On the electro-magnetic theory of light, however, a wave of light is accompanied by electric forces, and therefore by potential energy; thus waves of light must behave as if they possessed mass. It may be shown that it follows from the same principles that they must also possess momentum, the direction of the momentum being the direction along which the light is travelling; when the light is absorbed by an opaque substance the momentum in the light is communicated to the substance, which therefore behaves as if the light pressed upon it. The pressure exerted by light was shown by Maxwell (Electricity and Magnetism, 3rd ed., p. 440) to be a consequence of his electro-magnetic theory, its existence has been established by the experiment of Lebedew, of Nichols and Hull, and of Poynting.
We have hitherto been considering mass from the point of view that the constitution of matter is electrical; we shall proceed to consider the question of weight from the same point of view. The relation between mass and weight Weight. is, while the simplest in expression, perhaps the most fundamental and mysterious property possessed by matter. The weight of a body is proportional to its mass, that is if the weights of a number of substances are equal the masses will be equal, whatever the substances may be. This result was verified to a considerable degree of approximation by Newton by means of experiments with pendulums; later, in 1830 Bessel by a very extensive and accurate series of experiments, also made on pendulums, showed that the ratio of mass to weight was certainly to one part in 60,000 the same for all the substances examined by him, these included brass, silver, iron, lead, copper, ivory, water.
The constancy of this ratio acquires new interest when looked at from the point of view of the electrical constitution of matter. We have seen that the atoms of all bodies contain corpuscles, that the mass of a corpuscle is only 1⁄1700 of the mass of an atom of hydrogen, that it carries a constant charge of negative electricity, and that its mass is entirely due to this charge, and can be regarded as arising from ether gripped by the lines of force starting from the electrical charge. The question at once suggests itself, Is this kind of mass ponderable? does it add to the weight of the body? and, if so, is the proportion between mass and weight the same as for ordinary bodies? Let us suppose for a moment that this mass is not ponderable, so that the corpuscles increase the mass but not the weight of an atom. Then, since the mass of a corpuscle is 1⁄1700 that of an atom of hydrogen, the addition or removal of one corpuscle would in the case of an atom of atomic weight x alter the mass by one part in 1700 x, without altering the weight, this would produce an effect of the same magnitude on the ratio of mass to weight and would in the case of the atoms of the lighter elements be easily measurable in experiments of the same order of accuracy as those made by Bessel. If the number of corpuscles in the atom were proportional to the atomic weight, then the ratio of mass to weight would be constant whether the corpuscles were ponderable or not. If the number were not proportional there would be greater discrepancies in the ratio of mass to weight than is consistent with Bessel’s experiments if the corpuscles had no weight. We have seen there are other grounds for concluding that the number of corpuscles in an atom is proportional to the atom weight, so that the constancy of the ratio of mass to weight for a large number of substances does not enable us to determine whether or not mass due to charges of electricity is ponderable or not.
There seems some hope that the determination of this ratio for radio-active substances may throw some light on this point. The enormous amount of heat evolved by these bodies may indicate that they possess much greater stores of potential energy than other substances. If we suppose that the heat developed by one gramme of a radio-active substance in the transformations which it undergoes before it reaches the non-radio-active stage is a measure of the excess of the potential energy in a gramme of this substance above that in a gramme of non-radio-active substance, it would follow that a larger part of the mass was due to electric charges in radio-active than in non-radio-active substances; in the case of uranium this difference would amount to at least one part in 20,000 of the total mass. If this extra mass had no weight the ratio of mass to weight for uranium would differ from the normal amount by more than one part in 20,000, a quantity quite within the range of pendulum experiments. It thus appears very desirable to make experiments on the ratio of mass to weight for radio-active substances. Sir J. J. Thomson, by swinging a small pendulum whose bob was made of radium bromide, has shown that this ratio for radium does not differ from the normal by one part in 2000. The small quantity of radium available prevented the attainment of greater accuracy. Experiments just completed (1910) by Southerns at the Cavendish Laboratory on this ratio for uranium show that it is normal to an accuracy of one part in 200,000; indicating that in non-radio-active, as in radio-active, substances the electrical mass is proportional to the atomic weight.
Though but few experiments have been made in recent years on the value of the ratio of mass to weight, many important investigations have been made on the effect of alterations in the chemical and physical conditions on the weight of bodies. These have all led to the conclusion that no change which can be detected by our present means of investigation occurs in the weight of a body in consequence of any physical or chemical changes yet investigated. Thus Landolt, who devoted a great number of years to the question whether any change in weight occurs during chemical combination, came finally to the