قراءة كتاب The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2. With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2. With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
of our students.
Parts III and IV of this book are published in a separate volume, as a laboratory manual for qualitative analysis. They comprise the instructions for laboratory work introductory to systematic analysis (the study of reactions and of the analysis of groups, in Part III) and an outline for elementary systematic analysis (Part IV). The attempt has been made, in particular, to bring the laboratory work, which otherwise follows the usual lines of instruction in systematic analysis, also into closest relations to the development of the scientific foundations of analytical chemistry, as represented in Parts I and II. It is believed that the subject matter lends itself especially well to such a close interweaving of the two sides of the study, without any special loss of time to the student, and with the result, it is hoped, of a greatly increased interest on his part and an increased stimulus of the habit of scientific thought.
The following plan of work is used by the author with his classes: The first section (lasting eleven weeks) of the course in qualitative analysis is started with some seven to ten (according to the ability of the class) lectures or classroom exercises, given daily, and covering the first seven or the eight chapters of Part I. At the end of the second week the laboratory work is started. During the remainder of this section of the course, two hours of classroom work and eight hours of laboratory work per week are required, and, in this period, Part III, comprising the first half of the laboratory manual, is studied in the laboratory in closest connection with the classroom work on Part II of the book. As far as possible, the laboratory work on a given topic precedes the classroom work. This first course is followed by an eleven weeks' course in systematic analysis, covering Part IV of the book. A third (graduate) course, optional for students specializing in chemistry, is offered, in which very complex commercial and natural products are analyzed and in which special attention is also given to rare elements. During this course, particular care is taken to familiarize students with other works on qualitative analysis, such as the outlines of A. A. Noyes and Bray, and the special parts of Fresenius's manual.
Students who have been prepared in general chemistry along physicochemical lines, as represented, for instance, by Smith's textbooks, make more rapid and more easy progress in the first course than do students otherwise prepared. But the treatment of the subject is intended to make it possible for students, who have not paid particular attention to chemical equilibrium and to the modern theories of solution in their general chemistry course, to complete the course within the time limit indicated. Perhaps one-third of the students in an average class, in the past, have taken the course under these conditions and no special difficulty was encountered by them.
In the theoretical treatment the author is particularly indebted to the original articles and to the larger works of Arrhenius, van 't Hoff, Nernst, A. A. Noyes, Ostwald, and Walker. For the systematic analytical material acknowledgment is due, in particular, to Fresenius's "Qualitative Chemical Analysis," and to the important publications by A. A. Noyes and Bray in the Journal of the American Chemical Society. Some of the excellent methods of the latter authors have been adopted outright, as indicated in the text. For some special matters the author is indebted to the texts of W. A. Noyes and of Böttger. Constant references to his sources of information have been made by the author, partly as a matter of acknowledgment, and more particularly to give students and teachers the opportunity for more extended, first-hand reading on any topic of interest. References suitable for college students are indicated by the addition of (Stud.). In two or three instances, the original source of information has been forgotten and diligent search has failed to trace it. For use in preparing any future edition of the book, the author will be glad to have his attention called to the facts by authors.
The author wishes to express here his particular appreciation of the generous assistance given him by his former colleague, Prof. Alexander Smith of Columbia University, whose suggestions and advice, especially in the editing of the manuscript and proof, have been invaluable. He also wishes to make grateful acknowledgment to his colleagues, Profs. H. N. McCoy, H. Schlesinger, and Dr. Edith Barnard, to Prof. L. W. Jones of the University of Cincinnati, Prof. E. P. Schoch of the University of Texas, Prof. B. B. Freud of Armour Institute, and Prof. W. J. Hale of the University of Michigan, who have assisted him by reading the proofs or the manuscript, or by carrying out experimental studies underlying part of the work, or in other ways. Corrections of his mistakes of omission and commission, and suggestions, will be gratefully received by the author.
JULIUS STIEGLITZ.
Chicago, September, 1911.
CONTENTS
| PART I FUNDAMENTAL PRINCIPLES |
||
|---|---|---|
| CHAPTER | PAGE | |
| I. | Introduction | 3 |
| II. | Osmotic Pressure and the Theory of Solution, I | 8 |
| III. | Osmotic Pressure and the Theory of Solution, II | 21 |
| IV. | The Theory of Ionization: Ionization and Electrical Conductivity | 33 |
| V. | The Theory of Ionization, II: Ionization and Osmotic Pressure; Ionization and Chemical Activity | 67 |
| VI. | Chemical Equilibrium. The Law of Mass Action | 90 |
| VII. | Physical or Heterogeneous Equilibrium.—The Colloidal Condition | 118 |
| VIII. | Simultaneous Chemical and Physical Equilibrium.—The Solubility- or Ion-Product | 139 |

