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قراءة كتاب The Mirror of Literature, Amusement, and Instruction Volume 17, No. 480, March 12, 1831
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The Mirror of Literature, Amusement, and Instruction Volume 17, No. 480, March 12, 1831
and beautiful. With respect to the chemical constitution of ink, I may remark, that although, as usually prepared, it is a combination of the metallic salt or oxide, with all the four vegetable principles mentioned above; yet I am inclined to believe that the last three of them, so far from being essential, are the principal cause of the difficulty which we meet with in the formation of a perfect and durable ink. I endeavoured to prove this point by a series of experiments, of which the following is a brief abstract:—Having prepared a cold infusion of galls, I allowed a portion of it to remain exposed to the atmosphere, in a shallow capsule, until it was covered with a thick stratum of mould; the mould was removed by filtration, and the proper proportion of sulphate of iron being added to the clear fluid, a compound was formed of a deep black colour, which showed no farther tendency to mould, and which remained for a long time without experiencing any alteration.
Another portion of the same infusion of galls had solution of isinglass added to it until it no longer produced a precipitate; by employing the sulphate of iron, a black compound was produced, which, although paler than that formed from the entire fluid, appeared to be a perfect and durable ink. Lastly, a portion of the infusion of galls was kept for some time at the boiling temperature, by means of which a part of its contents became insoluble; this was removed by filtration, when, by the addition of the sulphate of iron, a very perfect and durable ink was produced. In the above three processes I conceive that a considerable part of the mucilage, the tan, and the extract, were respectively removed from the infusion, while the greater part of the gallic acid would be left in solution.
The three causes of deterioration in ink, the moulding, the precipitation of the black matter, and the loss of colour, as they are distinct operations, so we may presume that they depend on the operation of different proximate principles. It is probable that the moulding more particularly depends on the mucilage; and the precipitation on the extract, from the property which extractive matter possesses of forming insoluble compounds with metallic oxides. As to the operation of the tan, from its affinity for metallic salts, we may conjecture, that, in the first instance, it forms a triple compound with the gallic acid and the iron; and that, in consequence of the decomposition of the tan, this compound is afterwards destroyed. Owing to the difficulty, if not impossibility, of entirely depriving the infusion of galls of any one of its ingredients, without, in some degree, affecting the others, I was not able to obtain any results which can be regarded as decisive; but the general result of my experiments favours the above opinion, and leads me to conclude, that, in proportion as ink consists merely of the gallate of iron, it is less liable to decomposition, or to experience any kind of change.
The experiments to which I have alluded above, consisted in forming a standard infusion by macerating the powder of galls in five times its weight in water, and comparing this with other infusions, which had either been suffered to mould, from which the tan had been extracted by gelatine, or which had been kept for some time at the boiling temperature; and by adding to each of these respectively, both the recent solution of the sulphate of iron, and a solution of it, which had been exposed for some time to the atmosphere. The nature of the black compound produced was examined by putting portions of it into cylindrical jars, and observing the changes which they experienced with respect either to the formation of mould, the deposition of their contents, or any change of colour. The fluids were also compared by dropping portions of them upon white tissue paper, in which way both their colour and their consistence might be minutely ascertained. A third method was, to add together the respective infusions, and the solutions of the sulphate of iron, in a very diluted state, by which I was enabled to form a more correct comparison of the quantity, and of the state of the colouring matter, and of the degree of its solubility.
The practical conclusions that I think myself warranted in drawing from these experiments, are as follow:—In order to procure an ink which may be little disposed either to mould or to deposit its contents, and which, at the same time, may possess a deep black colour, not liable to fade, the galls should be macerated for some hours in hot water, and the fluid be filtered; it should then be exposed for about fourteen days to a warm atmosphere, when any mould which may have been produced must be removed. A solution of sulphate of iron is to be employed, which has also been exposed for some time to the atmosphere, and which, consequently, contains a certain quantity of the red oxide of iron diffused through it. I should recommend the infusion of galls to be made of considerably greater strength than is generally directed; and I believe that an ink, formed in this manner, will not necessarily require the addition of any mucilaginous substance to render it of a proper consistence.
I have only further to add, that one of the best substances for diluting ink, if it be, in the first instance, too thick for use, or afterwards become so by evaporation, is a strong decoction of coffee, which appears in no respect to promote the decomposition of the ink, while it improves its colour, and gives it an additional lustre.
THE SKETCH-BOOK.
FAIRY FAVOURS.—A VISION OF FAIRY LAND.
Once—whether in a dream, a waking vision, a poetical hallucination, or in sober reality, I know not—once was I favoured with a distinct and glorious vision of the Faries' Land! I found myself in a country more enchantingly beautiful than the warm, romantic dream of the poet has ever yet conceived:—therein bloomed trees, and plants, and flowers, in beauty and luxuriance never to fade; therein was the soft air strongly imbued with the ambrosial odour of the orient rose; but ever as a gentle breeze enfolded me, it seemed on its refreshing wings to bear the heavenly fragrance of unknown flowers. The sky was of an effulgent azure, altogether indescribable—but under the influence of stealing twilight, insensibly was it darkening, though the yet undimmed colours of sunset were inexpressibly varied and vivid. Radiant and exquisitely beautiful beings, fair miniatures of mortals, inhabited this charming region, wherein was assembled all that had power to inebriate the soul with pure and rapturous felicity, and imbue it with an intense perception of its immortality and blessedness. Now stole the faint, delicious sound of very distant bells—clear, silvery, and sweet—upon mine ear, as the tones of a well-touched harp: sad were they—luxuriously sad; and their unearthly melody infused into my bosom a repose unknown to mortality. As I listened with awe and rapture to that delicate minstrelsy, I seemed to become all soul; tears—far indeed from tears of sorrow—suffused my wondering eyes, and my heart, in the delirium of gratitude, raised itself in solemn thanksgivings to its Creator.
"Favoured mortal!" sighed near me a voice soft as a zephyr-breath. I turned, and beheld a constellation of the radiant inhabitants of this ethereal country clustered about a portal, whose frame-work was of shining stones, and whose firm, but slender bars, were of purest gold.—"Favoured mortal!" (the speaker was beside me)—"favoured beyond even thine own conception, know that thou art permitted to behold the Elfin Paradise—the true, the veritable Fairy Land. Pollute it not by the tone of mortal speech; to us are thy thoughts not unknown, and partially are we permitted to gratify thy desire for information. Thinkest thou—so indeed hath

