marks on a piece of white paper, and then press down firmly the paper it is proposed to employ over this. If the black ink marks are indistinguishable, the paper will do as regards this quality, as the light reflected from the surface which gives the impression of whiteness to the eye is much stronger than the light which penetrates through it, and is absorbed by the black lines. As to quality, it is best to trust to the manufacturer, those known as Saxe and Rives papers answering better than any other that we know of. The Rives is, when moist, a paper which is more easily torn than the Saxe, and, consequently, we recommend that the former be employed for small work, such as portraits, and the latter for large landscape prints.

In regard to the sizes to be albumenized, it must be left to the operator to say what will be the most useful to him. It is rarely advisable to albumenize less than a half sheet of paper, the whole size of which is about 22 by 18 inches; 11 by 18 is not an inconvenient size to manipulate. At any rate, a dish larger each way by a couple of inches than the paper must be procured, and put on a level table. The temperature of the room should be at least 90°, in fact, the hotter it is the more glossy will be the resulting paper. The solution, free from bubbles, is poured in, and should be of a depth of at least ¹/₂ an inch. Suppose the smaller size to be coated, before commencing, the paper is taken by the two opposite corners, the hands brought together, and the convex side brought on to the surface of the fluid; the hands are then separated, and the paper will gradually float on the surface. One corner should be gradually raised to see that all air-bubbles are absent. If there be any, they should be broken with the point of a glass rod, and the paper again lowered. Bubbles can usually be seen through the paper, and, instead of raising it, a few gentle taps with the finger over the spot will generally move the bubble to the edge of the paper. In practice, some have found it well to moisten the surface of the paper with a damp sponge, and when quite surface dry to albumenize it. This should, however, be unnecessary. The sheet should remain on the albumen a little over a minute, when it could be gently raised by one corner and allowed to drain over a basin; it is then caught by a couple of American clips and hung up to dry.[7]

Fig. 3.

Supposing a whole sheet is to be coated, it will be found more convenient to take the sheet by the corners of one end, one in each hand, and to lower the surface near the end of the dish, and gradually draw the paper over the side of the dish till the whole surface is flat. Bubbles can be got rid of as shown above.

Two large dishes are usually employed, and by the time the second sheet is floated in the second dish, the first sheet of paper is ready for removal from the first dish. The sheets, when slowly removed from the bath, are allowed to drain a few seconds, and then thrown over wooden rods of some two inches in diameter, which are removed to a rack, and placed near a trough to collect the drainings.[8] When drained sufficiently the rods are removed to other racks, and the paper allowed to dry spontaneously.

It is the practice of some albumenized paper manufacturers to hang the sheets over a line, uncoated side next to the line; but this is a mistake, as it will nearly always be found, on sensitising the paper and exposing it, that a mark is left across the paper corresponding to the part where the string touched the back of the paper.

In practice we have found that each sheet of paper takes up about ¹/₃ oz. of solution, and, of course, its equivalent quantity of salt. The principal difficulty in albumenizing paper is the occurrence of lines on the paper in the direction in which it was placed on the surface of the albumen. Any arrest of motion in floating the paper will cause them, but more usually it is due to imperfect beating up of the solution. Some papers are not readily coated with albumen, in which case the remedy given above may prove effectual; or a little solution of oxgall may be equally well applied. A want of gloss in the dried albumen may be due to too long a floating on the fluid, or to floating and drying the paper in too low a temperature. The explanation of the first cause is that albumen, when fresh, has an alkaline reaction, due to the presence of a small quantity of soda, which may be said to be its base, and any alkali will dissolve the gelatinous sizing of a paper. When the sizing is dissolved, instead of remaining on the surface, the albumen sinks into the paper, and thereby the gloss is lost.

When albumen is stale it no longer possesses this alkaline reaction, but has an acid reaction quite visible on the application of blue litmus paper to it; the blue colour disappears and is replaced by a red tint. When in the alkaline state, the paper is much more difficult to coat, but an acid condition means the production of inferior tones.

Rolling the Paper.—The paper, when dried, is often rolled with a heavy pressure to improve the gloss; a copper-plate press is found to answer admirably, placing the albumenized side next the bed. This rolling should not be necessary if attention be paid to the temperature of the preparation room. The higher the temperature the finer will be the gloss, as we have already said.

CHAPTER III.
THE SENSITIZING BATH FOR ALBUMENIZED PAPER.

To render albumenized paper sensitive to light it has to be treated with a solution of silver nitrate, and the most convenient method of applying it is to float it on a dish containing the silver salt in solution. The first point to consider is the strength of the solution. If we float albumenized paper (face downwards) on a solution of 10 grains of silver nitrate to the ounce of water, we shall find, what at first sight may seem to be remarkable, that the albumen will be dissolved away from the paper, and that there will be a precipitate left in the silver solution. Why is this?

It must be remembered that albumen is soluble in water: it is coagulated or insoluble in water when combined with silver nitrate. The fact is that the quantity of silver nitrate in the solution we have been experimenting with is too small. The water dissolves the albumen first, and then the silver has time to act upon it to form the insoluble albuminate. If we soak paper in common salt, and treat it in the same way with the same strength of solution, we shall find that this is not the case: the silver chloride will remain on the paper. From this we learn two facts.

1st. That the silver solution has a greater affinity for the chloride than for the albuminate, and that in an equal mixture of the two more chloride would be formed than albuminate; in other words, that the ammonium chloride would be totally converted into silver chloride long before the silver albuminate was formed.

2nd. That a certain strength of silver nitrate is necessary to prevent the