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قراءة كتاب The Story of Electricity

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The Story of Electricity

The Story of Electricity

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دار النشر: Project Gutenberg
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when allowed to rest, and hence it is useful for working electric bells and telephones. As shown in figure 16, it consists of a zinc rod with its connecting wire Z, and a carbon plate C with its binding screw, between two cakes M M of a mixture of black oxide of manganese, sulphur, and carbon, plunged in a solution of sal-ammoniac. The oxide of manganese relieves the carbon plate of its hydrogen. The strength of the solution is maintained by spare crystals of sal-ammoniac lying on the bottom of the cell, which is closed to prevent evaporation, but has a venthole for the escape of gas.

The Bichromate of Potash cell polarises more than the Leclanche, but yields a more powerful current for a short time. It consists, as shown in figure 17, of a zinc plate Z between two carbon plates C C immersed in a solution of bichromate of potash, sulphuric acid (vitriol), and water. The zinc is always lifted out of the solution when the cell is not in use. The gas which collects in the carbons, and weakens the cell, can be set free by raising the plates out of the liquid when the cell is not wanted. Stirring the solution has a similar effect, and sometimes the constancy of the cell is maintained by a circulation of the liquid. In Fuller's bichromate cell the zinc is amalgamated with mercury, which is kept in a pool beside it by means of a porous pot.

De la Rue's chloride of silver cell (fig. 18) is, from its constancy and small size, well adapted for medical and testing purposes. The "plates" are a little rod or pencil of zinc Z, and a strip or wire of silver S, coated with chloride of silver and sheathed in parchment paper. They are plunged in a solution of ammonium chloride A, contained in a glass phial or beaker, which is closed to suppress evaporation. A tray form of the cell is also made by laying a sheet of silver foil on the bottom of the shallow jar, and strewing it with dry chloride of silver, on which is laid a jelly to support the zinc plate. The jelly is prepared by mixing a solution of chloride of ammonium with "agar-agar," or Ceylon moss. This type permits the use of larger plates, and adapts the battery for lighting small electric lamps. Skrivanoff has modified the De la Rue cell by substituting a solution of caustic potash for the ammonium chloride, and his battery has been used for "star" lights, that is to say, the tiny electric lamps of the ballet. The Schanschieff battery, consisting of zinc and carbon plates in a solution of basic sulphate of mercury, is suitable for reading, mining, and other portable lamps.

The Latimer Clark "standard" cell is used by electricians in testing, as a constant electromotive force. It consists of a pure zinc plate separated from a pool of mercury by a paste of mercurous proto-sulphate and saturated solution of sulphate of zinc. Platinum wires connect with the zinc and mercury and form the poles of the battery, and the mouth of the glass cell is plugged with solid paraffin. As it is apt to polarise, the cell must not be employed to yield a current, and otherwise much care should be taken of it.

Dry cells are more cleanly and portable than wet, they require little or no attention, and are well suited for household or medical purposes. The zinc plate forms the vessel containing the carbon plate and chemical reagents. Figure 19 represents a section of the "E. C. C." variety, where Z is the zinc standing on an insulating sole I, and fitted with a connecting wire or terminal T (-), which is the negative pole. The carbon C is embedded in black paste M, chiefly composed of manganese dioxide, and has a binding screw or terminal T (+), which is the positive pole. The black paste is surrounded by a white paste Z, consisting mainly of lime and sal-ammoniac. There is a layer of silicate cotton S C above the paste, and the mouth is sealed with black pitch P, through which a waste-tube W T allows the gas to escape.

The Hellesen dry cell is like the "E. C. C.," but contains a hollow carbon, and is packed with sawdust in a millboard case. The Leclanche-Barbier dry cell is a modification of the Leclanche wet cell, having a paste of sal-ammoniac instead of a solution.

All the foregoing cells are called "primary," because they are generators of electricity. There are, however, batteries known as "secondary," which store the current as the Leyden jar stores up the discharge from an electrical machine.

In the action of a primary cell, as we have seen, water is split into its constituent gases, oxygen and hydrogen. Moreover, it was discovered by Carlisle and Nicholson in the year 1800 that the current of a battery could decompose water in the outer part of the circuit. Their experiment is usually performed by the. apparatus shown in figure 20, which is termed a voltameter, and consists of a glass vessel V, containing water acidulated with a little sulphuric acid to render it a better conductor, and two glass test-tubes OH inverted over two platinum strips or electrodes, which rise up from the bottom of the vessel and are connected underneath it to wires from the positive and negative poles of the battery C Z. It will be understood that the current enters the water by the positive electrode, and leaves it by the negative electrode.

When the power of the battery is sufficient the water in the vessel is decomposed, and oxygen being the negative element, collects at the positive foil or electrode, which is covered by the tube O. The hydrogen, on the other hand, being positive, collects at the negative foil under the tube H. These facts can be proved by dipping a red-hot wick or taper into the gas of the tube O and seeing it blaze in presence of the oxygen which feeds the combustion, then dipping the lighted taper into the gas of the tube H and watching it burn with the blue flame of hydrogen. The volume of gas at the CATHODE or negative electrode is always twice that at the ANODE or positive electrode, as it should be according to the known composition of water.

Now, if we disconnect the battery and join the two platinum electrodes of the voltameter by a wire, we shall find a current flowing out of the voltameter as though it were a battery, but in the reverse direction to the original current which decomposed the water. This "secondary" or reacting current is evidently due to the polarisation of the foils—that is to say, the electro- positive and electro-negative gases collected on them.

Professor Groves constructed a gas battery on this principle, the plates being of platinum and the two gases surrounding them oxygen and hydrogen, but the most useful development of it is the accumulator or storage battery.

The first practicable secondary battery of Gaston Plante was made of sheet lead plates or electrodes, kept apart by linen cloth soaked in dilute sulphuric acid, after the manner of Volta's pile. It was "charged" by connecting the plates to a primary battery, and peroxide of lead (PbO2) was formed on one plate and spongy lead (Pb) on the other. When the charging current was cut off the peroxide plate became the positive and the spongy plate the negative pole of the secondary cell.

Faure improved the Plante cell by adding a paste of red lead or minium (Pb204) and dilute sulphuric acid (H2SO4), by which a large quantity of peroxide and spongy lead could be formed on the plates. Sellon and Volckmar increased its efficiency by putting the paste into holes cast in the lead. The "E. P. S." accumulator of the Electrical Power Storage Company is illustrated in figure 21, and consists of a glass or teak box containing two sets of leaden grids perforated with holes, which are primed with the paste and steeped in dilute sulphuric acid. Alternate grids are joined to the poles of a charging battery or generator, those connected to the positive pole being converted into peroxide of lead and the others into spongy lead. The terminal of the peroxide plates, being the positive pole of the

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