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قراءة كتاب Five of Maxwell's Papers

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Five of Maxwell's Papers

Five of Maxwell's Papers

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دار النشر: Project Gutenberg
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probable that the mean distance of their particles at the ordinary temperature and pressure is a quantity of the same order of magnitude as a millionth of a millimetre, and Sir William Thomson has since[2] shewn, by several independent lines of argument, drawn from phenomena so different in themselves as the electrification of metals by contact, the tension of soap-bubbles, and the friction of air, that in ordinary solids and liquids the average distance between contiguous molecules is less than the hundred-millionth, and greater than the two-thousand-millionth of a centimetre.

[1] Phil. Mag., Aug. 1868. [2] Nature, March 31, 1870.

These, of course, are exceedingly rough estimates, for they are derived from measurements some of which are still confessedly very rough; but if at the present time, we can form even a rough plan for arriving at results of this kind, we may hope that, as our means of experimental inquiry become more accurate and more varied, our conception of a molecule will become more definite, so that we may be able at no distant period to estimate its weight with a greater degree of precision.

A theory, which Sir W. Thomson has founded on Helmholtz's splendid hydrodynamical theorems, seeks for the properties of molecules in the ring vortices of a uniform, frictionless, incompressible fluid. Such whirling rings may be seen when an experienced smoker sends out a dexterous puff of smoke into the still air, but a more evanescent phenomenon it is difficult to conceive. This evanescence is owing to the viscosity of the air; but Helmholtz has shewn that in a perfect fluid such a whirling ring, if once generated, would go on whirling for ever, would always consist of the very same portion of the fluid which was first set whirling, and could never be cut in two by any natural cause. The generation of a ring-vortex is of course equally beyond the power of natural causes, but once generated, it has the properties of individuality, permanence in quantity, and indestructibility. It is also the recipient of impulse and of energy, which is all we can affirm of matter; and these ring-vortices are capable of such varied connexions and knotted self-involutions, that the properties of differently knotted vortices must be as different as those of different kinds of molecules can be.

If a theory of this kind should be found, after conquering the enormous mathematical difficulties of the subject, to represent in any degree the actual properties of molecules, it will stand in a very different scientific position from those theories of molecular action which are formed by investing the molecule with an arbitrary system of central forces invented expressly to account for the observed phenomena.

In the vortex theory we have nothing arbitrary, no central forces or occult properties of any other kind. We have nothing but matter and motion, and when the vortex is once started its properties are all determined from the original impetus, and no further assumptions are possible.

Even in the present undeveloped state of the theory, the contemplation of the individuality and indestructibility of a ring-vortex in a perfect fluid cannot fail to disturb the commonly received opinion that a molecule, in order to be permanent, must be a very hard body.

In fact one of the first conditions which a molecule must fulfil is, apparently, inconsistent with its being a single hard body. We know from those spectroscopic researches which have thrown so much light on different branches of science, that a molecule can be set into a state of internal vibration, in which it gives off to the surrounding medium light of definite refrangibility—light, that is, of definite wave-length and definite period of vibration. The fact that all the molecules (say, of hydrogen) which we can procure for our experiments, when agitated by heat or by the passage of an electric spark, vibrate precisely in the same periodic time, or, to speak more accurately, that their vibrations are composed of a system of simple vibrations having always the same periods, is a very remarkable fact.

I must leave it to others to describe the progress of that splendid series of spectroscopic discoveries by which the chemistry of the heavenly bodies has been brought within the range of human inquiry. I wish rather to direct your attention to the fact that, not only has every molecule of terrestrial hydrogen the same system of periods of free vibration, but that the spectroscopic examination of the light of the sun and stars shews that, in regions the distance of which we can only feebly imagine, there are molecules vibrating in as exact unison with the molecules of terrestrial hydrogen as two tuning-forks tuned to concert pitch, or two watches regulated to solar time.

Now this absolute equality in the magnitude of quantities, occurring in all parts of the universe, is worth our consideration.

The dimensions of individual natural bodies are either quite indeterminate, as in the case of planets, stones, trees, &c., or they vary within moderate limits, as in the case of seeds, eggs, &c.; but even in these cases small quantitative differences are met with which do not interfere with the essential properties of the body.

Even crystals, which are so definite in geometrical form, are variable with respect to their absolute dimensions.

Among the works of man we sometimes find a certain degree of uniformity.

There is a uniformity among the different bullets which are cast in the same mould, and the different copies of a book printed from the same type.

If we examine the coins, or the weights and measures, of a civilized country, we find a uniformity, which is produced by careful adjustment to standards made and provided by the state. The degree of uniformity of these national standards is a measure of that spirit of justice in the nation which has enacted laws to regulate them and appointed officers to test them.

This subject is one in which we, as a scientific body, take a warm interest; and you are all aware of the vast amount of scientific work which has been expended, and profitably expended, in providing weights and measures for commercial and scientific purposes.

The earth has been measured as a basis for a permanent standard of length, and every property of metals has been investigated to guard against any alteration of the material standards when made. To weigh or measure any thing with modern accuracy, requires a course of experiment and calculation in which almost every branch of physics and mathematics is brought into requisition.

Yet, after all, the dimensions of our earth and its time of rotation, though, relatively to our present means of comparison, very permanent, are not so by any physical necessity. The earth might contract by cooling, or it might be enlarged by a layer of meteorites falling on it, or its rate of revolution might slowly slacken, and yet it would continue to be as much a planet as before.

But a molecule, say of hydrogen, if either its mass or its time of vibration were to be altered in the least, would no longer be a molecule of hydrogen.

If, then, we wish to obtain standards of length, time, and mass which shall be absolutely permanent, we must seek them not in the dimensions, or the motion, or the mass of our planet, but in the wave-length, the period of vibration, and the absolute mass of these imperishable and unalterable and perfectly similar molecules.

When we find that here, and in the starry heavens, there are innumerable multitudes of little bodies of exactly the same mass, so many, and no more, to the grain, and vibrating in exactly the same time, so many times, and no more, in a second, and when we reflect that no power in nature

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